ELECTROSYNTHESIS IN SYSTEMS OF 2 IMMISCIBLE LIQUIDS AND A PHASE-TRANSFER CATALYST .6. THE INFLUENCE OF ZINC-CHLORIDE ON THE CHLORINATION OF NAPHTHALENE

被引：6

作者：

IBRISAGIC, Z ^{[1
]}

PLETCHER, D ^{[1
]}

BROOKS, WN ^{[1
]}

HEALY, KP ^{[1
]}

机构：

[1] ICI PLC,NEW SCI GRP,RUNCORN WA7 4QE,CHESHIRE,ENGLAND

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1985年 / 15卷 / 05期

关键词：

CATALYSTS; -; ELECTROLYSIS; NAPHTHALENE; Chlorination;

D O I：

10.1007/BF00620568

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The influence of zinc chloride on the chlorination of naphthalene by electrolysis in a water-methylene chloride emulsion and using tetrabutylammonium ion as a phase transfer catalyst is described. It is shown that when the aqueous medium contains both NaCl and ZnCl//2 it is the anion ZnCl//4**2** minus which transfers into the organic phase and it is confirmed that the presence of ZnCl//2 in the electrolyte is, indeed, beneficial. The electrolyses have been carried out in both divided and undivided cells and in both the organic yield of 1-chloronaphthalene can exceed 80% but the former is better from the viewpoint of speed of electrolysis; in the divided cell, the conversion was 85% (cf. typically 60% in the undivided cell) after the passage of 2. 3 F mol** minus **1 of naphthalene. Possible mechanisms for the effect of ZnCl//2 are discussed.

引用

页码：719 / 725

页数：7

共 5 条

[1] ELECTROSYNTHESIS IN SYSTEMS OF 2 IMMISCIBLE LIQUIDS AND A PHASE-TRANSFER CATALYST .5. THE ANODIC CHLORINATION OF NAPHTHALENE [J].