TETRA-TERT-BUTYLPYRAZOLE AND TETRA-TERT-BUTYLTHIOPHENE

被引:18
作者
KREBS, AW [1 ]
FRANKEN, E [1 ]
MULLER, M [1 ]
COLBERG, H [1 ]
CHOLCHA, W [1 ]
WILKEN, J [1 ]
OHRENBERG, J [1 ]
ALBRECHT, R [1 ]
WEISS, E [1 ]
机构
[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,W-2000 HAMBURG 13,GERMANY
关键词
OVERCROWDED COMPOUNDS; PYRAZOLES; THIOPHENES; 1,2,3-THIADIAZOLES;
D O I
10.1016/S0040-4039(00)61096-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Tetra-tert.butylpyrazole (4) and tetra-tert.butylthiophene (11) were prepared starting from the seven membered cycloalkyne 1 and a reductive desulfurization in the last step. Some reactions of 4 and 11 are described. X-ray structural analyses of 11 and the corresponding S,S-dioxide were carried out.
引用
收藏
页码:5947 / 5950
页数:4
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