DYNAMICS OF REACTION OF [MESO-TETRAKIS(2,6-DIMETHYL-3-SULFONATOPHENYL)PORPHINATO]-IRON(III) HYDRATE WITH TERT-BUTYL HYDROPEROXIDE IN AQUEOUS-SOLUTION .2. ESTABLISHMENT OF A MECHANISM THAT INVOLVES HOMOLYTIC O-O BOND BREAKING AND ONE-ELECTRON OXIDATION OF THE IRON(III) PORPHYRIN

被引：65

作者：

BALASUBRAMANIAN, PN ^{[1
]}

SMITH, JRL ^{[1
]}

DAVIES, MJ ^{[1
]}

KAARET, TW ^{[1
]}

BRUICE, TC ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1989年 / 111卷 / 04期

关键词：

D O I：

10.1021/ja00186a050

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1477 / 1483

页数：7

共 24 条

[1] CATALASE MODELING .2. DYNAMICS OF REACTION OF A WATER-SOLUBLE AND NON-MU-OXO DIMER FORMING MANGANESE(III) PORPHYRIN WITH HYDROGEN-PEROXIDE [J].

BALASUBRAMANIAN, PN ;

SCHMIDT, ES ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (25) :7865-7873

[2] A KINETIC-STUDY OF THE EPOXIDATION OF 2,3-DIMETHYL-2-BUTENE BY TERT-BUTYL HYDROPEROXIDE CATALYZED BY IMIDAZOLE LIGATED (MESO-TETRAPHENYLPORPHINATO)MANGANESE(III) [J].

BALASUBRAMANIAN, PN ;

SINHA, A ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (05) :1456-1462

[3]

BEUTTNER GR, 1978, BIOCHEM BIOPH RES CO, V83, P69

[4] REACTIONS OF IRON PORPHYRINS WITH METHYL RADICALS [J].

BRAULT, D ;

NETA, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (10) :2705-2710

[5] THE MECHANISM OF HYDROPEROXIDE O-O BOND SCISSION ON REACTION OF HYDROPEROXIDES WITH IRON(III) PORPHYRINS [J].

BRUICE, TC ;

BALASUBRAMANIAN, PN ;

LEE, RW ;

SMITH, JRL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (23) :7890-7892

[6] SPECTRAL AND ELECTROCHEMICAL IDENTIFICATION OF IRON(IV) OXO-PORPHYRIN AND IRON(IV) OXO-PORPHYRIN PI-CATION SPECIES [J].

CALDERWOOD, TS ;

LEE, WA ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) :8272-8273

[7] ELECTROCHEMICAL GENERATION OF IRON(IV)-OXO PORPHYRINS AND IRON(IV)-OXO PORPHYRIN PI-CATION RADICALS [J].

CALDERWOOD, TS ;

BRUICE, TC .

INORGANIC CHEMISTRY, 1986, 25 (21) :3722-3724

[8] DETECTION OF PEROXYL AND ALKOXYL RADICALS PRODUCED BY REACTION OF HYDROPEROXIDES WITH HEME-PROTEINS BY ELECTRON-SPIN RESONANCE SPECTROSCOPY [J].

DAVIES, MJ .

BIOCHIMICA ET BIOPHYSICA ACTA, 1988, 964 (01) :28-35

[9] ABSOLUTE RATE CONSTANTS OF ALKOXYL RADICAL REACTIONS IN AQUEOUS-SOLUTION [J].

ERBENRUSS, M ;

MICHEL, C ;

BORS, W ;

SARAN, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (09) :2362-2365

[10] MODEL COMPOUNDS FOR R-STATE AND T-STATE HEMOGLOBINS [J].

GEIBEL, J ;

CANNON, J ;

CAMPBELL, D ;

TRAYLOR, TG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (11) :3575-3585

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