S-TRANS-1,3-DIENES AS LIGANDS FOR CATIONIC GROUP-8 METAL CENTERS

被引：41

作者：

BENYUNES, SA ^{[1
]}

DAY, JP ^{[1
]}

GREEN, M ^{[1
]}

ALSAADOON, AW ^{[1
]}

WARING, TL ^{[1
]}

机构：

[1] UNIV LONDON KINGS COLL,DEPT CHEM,LONDON WC2R 2LS,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3-Dienes very frequently assume an s-cis-conformation upon coordination to metal centers. The Ru-complex 1 is the first cationic s-trans-diene complex which is stable in solution at room temperature. Such complexes are conceivable as reactive intermediates in the catalytic reaction of conjugated dienes.

引用

页码：1416 / 1417

页数：2

共 11 条

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