COUPLING OF (AMINO)ALKYLCHLOROSILANES WITH LITHIUM - NEW ACCESS TO SYMMETRICAL DIFUNCTIONAL AND TETRAFUNCTIONAL ALKYLDISILANES

被引：39

作者：

TAMAO, K

KAWACHI, A

ITO, Y

机构：

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 02期

关键词：

D O I：

10.1021/om00026a050

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Homocoupling reactions of amino- and diaminoalkylchlorosilanes with lithium metal proceed readily in THF at room temperature to form the corresponding symmetrical diamino- and tetraaminoalkyldisilanes, respectively, in high yields, which are transformed into chloro- and alkoxyalkyldisilanes under mild conditions.

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页码：580 / 582

页数：3

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