(D2O)-O-16 AND (D2O)-O-18 TRANSITION FREQUENCIES AND STRENGTHS IN THE NU(2)-BANDS

被引:50
作者
TOTH, RA
机构
[1] California Institute of Technology, Jet Propulsion Laboratory, Pasadena
关键词
D O I
10.1006/jmsp.1993.1267
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Measurements of line positions and absolute linestrengths of D2O in the ν2 band were made with a Fourier-transform spectrometer at a resolution of 5 × 10-3 cm-1. The measured line frequencies of D216O and D218O were used along with additional data taken from studies of pure rotational transitions in an analysis to obtain rotational energies of levels in the (000) and (010) states. Measurements of the linestrengths were fitted by least-squares and the results are in exeellent agreement with the 899 and 438 experimental transitions of D216O and D218O, respectively, included in the analyses. These results provide a more accurate representation of the line positions and linestrengths for the (010)-(000) band than that currently available. © 1993 Academic Press Inc.
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收藏
页码:41 / 54
页数:14
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