PREPARATION AND CHARACTERIZATION OF CIS-A-[RU(BPY)(2)(PY)(O)](2+)

被引：37

作者：

HUA, X ^{[1
]}

LAPPIN, AG ^{[1
]}

机构：

[1] UNIV NOTRE DAME,DEPT CHEM & BIOCHEM,NOTRE DAME,IN 46556

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 04期

关键词：

D O I：

10.1021/ic00108a036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrolysis of optically active cis-[Ru(bpy)(2)(py)Cl]-(PF6) yields cis-[Ru(bpy)(2)(py)(H2O)](ClO4)(2) with 80% retention of configuration. The oxidation to cis-[Ru(bpy)(2)(py)(O)](ClO4)(2) is also found to involve retention of the absolute configuration. This optically active oxidant is slow to racemize and has been characterized by circular dichroism spectroscopy. Asymmetric oxidation of a prochiral methyl p-tolyl sulfide to a chiral sulfoxide by the chiral oxidant complex is observed with 30% ee in a water-acetonitrile mixture.

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页码：992 / 994

页数：3

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