The preparation, characterisation and low temperature x-ray structure of Ru-6(eta(2)-mu(4)-CO)(2)(CO)(13)(eta(6)-C(6)Me(6))

被引：12

作者：

Blake, AJ ^{[1
]}

Dyson, PJ ^{[1
]}

Ingham, SL ^{[1
]}

Johnson, BFG ^{[1
]}

Martin, CM ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

INORGANICA CHIMICA ACTA | 1995年 / 240卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

crystal structures; Ruthenium cluster; hexamethylbenzene;

D O I：

10.1016/0020-1693(95)04512-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new organometallic cluster Ru-6(eta(2)-mu(4)-CO)(2)(CO)(13)(eta(6)-C(6)Me(6)) has been prepared by the thermolysis of Ru-3(CO)(12) with hexamethylbenzene in octane and characterised by a single crystal X-ray diffraction study. If is isostructural with the known cluster Ru-6(eta(2)-mu(4)-CO)(2)(CO)(13)(eta(6)-C(6)H(3)Me(3)) and the metal core constitutes the same tetrahedral Ru-4 unit with two edge-bridging Ru atoms. The mesitylene derivative has been shown to undergo rearrangement to afford the octahedral carbido cluster Ru6C(CO)(14)(eta(6)-C(6)H(3)Me(3)), but this conversion is not observed for the new hexamethylbenzene derivative.

引用

页码：29 / 32

页数：4

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