PARALLELISM BETWEEN NUCLEOPHILICALLY SOLVENT-ASSISTED AND PHENYL-ASSISTED REACTIONS - POSSIBLE EXISTENCE OF NUCLEOPHILICALLY BETA-PHENYL-SOLVATED ION-PAIRS

被引：6

作者：

LAUREILLARD, J ^{[1
]}

CASADEVALL, A ^{[1
]}

CASADEVALL, E ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM, CHIM BIOORGAN & ORGAN PHYS LAB, CNRS, ERA 685, F-75231 PARIS 05, FRANCE

来源：

HELVETICA CHIMICA ACTA | 1984年 / 67卷 / 01期

关键词：

D O I：

10.1002/hlca.19840670142

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：352 / 360

页数：9

共 39 条

[1]

Bentley T.W., 1977, ADV PHYS ORG CHEM, V14, P32

[2] THE SN2-SN1 SPECTRUM .3. SOLVOLYSES OF SECONDARY AND TERTIARY ALKYL SULFONATES IN FLUORINATED ALCOHOLS - FURTHER EVIDENCE FOR THE SN2 (INTERMEDIATE) MECHANISM [J].

BENTLEY, TW ;

BOWEN, CT ;

MORTEN, DH ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (18) :5466-5475

[3] SN2-SN1 SPECTRUM .1. ROLE OF NUCLEOPHILIC SOLVENT ASSISTANCE AND NUCLEOPHILICALLY SOLVATED ION-PAIR INTERMEDIATES IN SOLVOLYSES OF PRIMARY AND SECONDARY ARENESULFONATES [J].

BENTLEY, TW ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (24) :7658-7666

[4] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .I. ROLE OF EQUILIBRATING CATIONS IN CARBONIUM ION CHEMISTRY . NATURE OF INTERMEDIATES INVOLVED IN SOLVOLYSIS OF SYMMETRICALLY SUBSTITUTED BETA-PHENYLETHYL DERIVATIVES [J].

BROWN, HC ;

MORGAN, KJ ;

CHLOUPEK, FJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (10) :2137-&

[5] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .2. NATURE OF INTERMEDIATES INVOLVED IN SOLVOLYSIS OF SYMMETRICALLY SUBSTITUTED BETA-ANISYLETHYL DERIVATIVES [J].

BROWN, HC ;

BERNHEIM.R ;

KIM, CJ ;

SCHEPPEL.SE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (02) :370-&

[6]

Capon B., 1976, NEIGHBORING GROUP PA, V1

[7] CONFORMATION AND REACTIVITY OF (4,N,O) BICYCLIC SYSTEMS AT TRANSCONFORMATION AND REACTIVITY OF (4,N,O) BICYCLIC SYSTEMS AT TRANS JUNCTION .19. SYNTHESIS, CONFORMATION AND CONFIGURATION OF 4-METHYL AND 4-HALOBICYCLO(4,2,0) OCTAN-3-OLS AND-OCTAN-3-ONES - EPIMERIZATION EQUILIBRIA OF ALPHA-SUBSTITUTED BICYCLO(4,2,0)OCTANONESS [J].

CASADEVALL, E ;

LARGEAU, C ;

MOREAU, P ;

BOUISSET, M .

TETRAHEDRON, 1973, 29 (13) :1865-1875

[8] MECHANISM OF ELIMINATION REACTIONS .7. SOLVENT EFFECTS ON RATES AND PRODUCT-PROPORTIONS IN UNI-MOLECULAR AND BI-MOLECULAR SUBSTITUTION AND ELIMINATION REACTIONS OF ALKYL HALIDES AND SULPHONIUM SALTS IN HYDROXYLIC SOLVENTS [J].

COOPER, KA ;

DHAR, ML ;

HUGHES, ED ;

INGOLD, CK ;

MACNULTY, BJ ;

WOOLF, LI .

JOURNAL OF THE CHEMICAL SOCIETY, 1948, (DEC) :2043-2049

[9] STUDIES IN STEREOCHEMISTRY .19. THE QUESTION OF THE STRUCTURE OF THE PHENONIUM TOSYLATE ION-PAIRS THAT OCCUR AS INTERMEDIATES IN THE SOLVOLYSES OF THE STEREOISOM RIC 4-PHENYL-3-HEXYL TOSYLATES [J].

CRAM, DJ ;

ELHAFEZ, FAA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (13) :3189-3195

[10] STUDIES IN STEREOCHEMISTRY .28. REACTIVITY DIFFERENCES BETWEEN DIASTEREOMERS IN THE WAGNER-MEERWEIN REARRANGEMENT [J].

CRAM, DJ ;

NYQUIST, HL ;

ABDELHAFEZ, FA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (11) :2876-2888

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