CRYSTAL-STRUCTURE AND SPECTRA OF TRICHLORO-PARA-CHLOROBENZOYL-2-FURALDEHYDOHYDRAZONO BISMUTH(III)

被引：13

作者：

KYRIAKIDIS, CE ^{[1
]}

CHRISTIDIS, PC ^{[1
]}

RENTZEPERIS, PJ ^{[1
]}

TOSSIDIS, IA ^{[1
]}

BOLOS, CA ^{[1
]}

机构：

[1] ARISTOTELIAN UNIV SALONIKA,INORGAN CHEM LAB,SALONIKA,GREECE

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1990年 / 193卷 / 1-2期

关键词：

CRYSTAL STRUCTURE; SPECTRA; C12H9BICL4N2O2; CHLOROBENZOYLHYDRAZONE BISMUTH(III) COMPLEX;

D O I：

10.1524/zkri.1990.193.1-2.101

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal sturcture of the title compound has been determined from three-dimensional X-ray diffraction data. The structure is monoclinic, space group P2(1)/c, with a = 12.873(4), b = 7.134(1), c = 19.446(7) angstrom, beta = 111.29(3)-degrees, V = 1663.97 angstrom3 and Z = 4. The structure was solved by direct methods and refined by least-squares to a final R = 0.039 (R(w) = 0.039, R(g) = 0.050). The complex forms polymeric chains of the type -Cl-Bi...Cl-Bi...extending approximately parallel to the b axis. Bismuth is in a distorted pentagonal bipyramidal coordination ]Bi-Cl: 2.510(4) - 2.562(5) angstrom for the bridging and 2.771(3) - 2.909(5) angstrom for the non-bridging chlorine atoms, Bi-O: 2.424(8) - 2.986(9) angstrom, Bi-N: 2.654(10) angstrom]. The molecular cohesion within a polymeric chain is enhanced by hydrogen bonding, while the chains are held together by regular van der Waals forces.

引用

页码：101 / 110

页数：10

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