AN EELS AND STATIC SIMS STUDY OF THE ADSORPTION AND DECOMPOSITION OF PROPENE ON RU(0001)

被引：21

作者：

SAKAKINI, BH ^{[1
]}

RANSLEY, IA ^{[1
]}

ODUOZA, CF ^{[1
]}

VICKERMAN, JC ^{[1
]}

CHESTERS, MA ^{[1
]}

机构：

[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

来源：

SURFACE SCIENCE | 1992年 / 271卷 / 1-2期

关键词：

D O I：

10.1016/0039-6028(92)90878-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron energy loss spectroscopy (EELS) and static secondary ion mass spectrometry (SSIMS) were used to investigate the adsorption and decomposition of propene on the Ru(0001) single-crystal surface. Propene was found to adsorb at 153 K predominantly in a molecular form, but with some dehydrogenation. Annealing the surface to 203 K produced adsorbed propylidyne species. At 233 K ethylidyne and propylidyne were found to coexist but by 293 K the propylidyne species had decomposed completely to give ethylidyne and some CxH species on the surface.

引用

页码：227 / 236

页数：10

共 21 条

[1] THE CHARACTERIZATION OF SURFACE ACETYLENE AND ETHYLENE SPECIES ON PT(111) BY ANGLE RESOLVED PHOTOEMISSION USING SYNCHROTRON RADIATION [J].

ALBERT, MR ;

SNEDDON, LG ;

EBERHARDT, W ;

GREUTER, F ;

GUSTAFSSON, T ;

PLUMMER, EW .

SURFACE SCIENCE, 1982, 120 (01) :19-37

[2] THE USE OF THERMAL-DESORPTION AND ELECTRON-ENERGY LOSS SPECTROSCOPY FOR THE DETERMINATION OF THE STRUCTURES OF UNSATURATED-HYDROCARBONS CHEMISORBED ON METAL SINGLE-CRYSTAL SURFACES .1. ALK-1-ENES ON PT(111) [J].

AVERY, NR ;

SHEPPARD, N .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1986, 405 (1828) :1-25

[3] BONDING AND THERMAL-DECOMPOSITION OF PROPYLENE, PROPADIENE, AND METHYLACETYLENE ON THE RH(111) SINGLE-CRYSTAL SURFACE [J].

BENT, BE ;

MATE, CM ;

CROWELL, JE ;

KOEL, BE ;

SOMORJAI, GA .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (06) :1493-1502

[4]

BROWN A, 1984, SURF SCI, V10, P261

[5] INFRARED SPECTROSCOPIC COMPARISON OF THE CHEMISORBED SPECIES FROM ETHENE, PROPENE, BUT-1-ENE AND CIS-BUT-2-ENE AND TRANS-BUT-2-ENE ON PT(111) AND ON A PLATINUM SILICA CATALYST [J].

CHESTERS, MA ;

DELACRUZ, C ;

GARDNER, P ;

MCCASH, EM ;

PUDNEY, P ;

SHAHID, G ;

SHEPPARD, N .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (15) :2757-2763

[6] INTRAMOLECULAR INTERACTIONS .16. CALCULATION OF VIBRATION FREQUENCIES OF 1,1,1-TRICHLOROPROPANE AND ROTATION ISOMERS OF 1,1,1-TRICHLORO-3-HALOPROPANES [J].

GOURSOTL.A ;

CARLESLO.M ;

POUZARD, G ;

BODOT, H .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1973, A 29 (07) :1497-1507

[7] INTERACTION OF ETHYLENE WITH THE RU(001) SURFACE [J].

HILLS, MM ;

PARMETER, JE ;

MULLINS, CB ;

WEINBERG, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (13) :3554-3562

[8] STRUCTURE AND BONDING OF CHEMISORBED ETHYLENE AND ETHYLIDYNE ON PT(111) FROM NEAR EDGE X-RAY ABSORPTION FINE-STRUCTURE SPECTROSCOPY AND MULTIPLE-SCATTERING CALCULATIONS [J].

HORSLEY, JA ;

STOHR, J ;

KOESTNER, RJ .

JOURNAL OF CHEMICAL PHYSICS, 1985, 83 (06) :3146-3153

[9] DYNAMICAL LEED STUDY OF C2H2 AND C2H4 CHEMISORPTION ON PT(111) - EVIDENCE FOR ETHYLIDYNE (-C-CH3) GROUP [J].

KESMODEL, LL ;

DUBOIS, LH ;

SOMORJAI, GA .

CHEMICAL PHYSICS LETTERS, 1978, 56 (02) :267-271

[10] MOLECULAR-STRUCTURE OF HYDROCARBON MONOLAYERS ON METAL-SURFACES [J].

KOESTNER, RJ ;

VANHOVE, MA ;

SOMORJAL, GA .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (02) :203-213

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