PEROVSKITE-LIKE INTERGROWTH STRUCTURE OF THE REDUCED CUPRATE ND2CUO3.5 - A COMBINATION OF DEFECT AND EXCESS OXYGEN NONSTOICHIOMETRY PHENOMENA

被引：14

作者：

CHOISNET, J

MOURON, P

CRESPIN, M

VANAKEN, PA

MULLER, WF

机构：

[1] UNIV ORLEANS,CNRS,CTR RECH MAT DIVISEE,F-45071 ORLEANS 2,FRANCE

[2] TH DARMSTADT,INST MINERAL,D-64287 DARMSTADT,GERMANY

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1994年 / 4卷 / 06期

关键词：

D O I：

10.1039/jm9940400895

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure of the cuprate Nd2CuO3.5, prepared by hydrogen reduction of Nd2CuO4 at 290-degrees-C, is reported. The oxygen non-stoichiometry, deduced from X-ray powder diffraction calculations, points to the simultaneous existence of defect and excess phenomena, up to now known only separately, as in Sr2CuO3 and LaSrNiO3.1 (oxygen defect) and La2NiO4.18 (oxygen excess). Special emphasis is devoted to the neodymium oxygen slab whose composition is modelled in terms of the as-calculated formula NdO0.9/O0.6/NdO0.9. The structure of such slabs combines the crystal chemical trends of NaCl and fluorite as observed in the K2NiF4 and Nd2CuO4 structures, respectively.

引用

页码：895 / 898

页数：4

共 14 条

[1] A RE-INVESTIGATION OF THE CRYSTAL-STRUCTURE OF LA2NIO4 - NON STOICHIOMETRY AND LAO LAYERS [J].