COPPER(II) COMPLEXES OF 6-METHYL-2-FORMYLPYRIDINE N-4-SUBSTITUED THIOSEMICARBAZONES

被引：28

作者：

WEST, DX ^{[1
]}

DIETRICH, SL ^{[1
]}

THIENTANAVANICH, I ^{[1
]}

BROWN, CA ^{[1
]}

机构：

[1] ILLINOIS STATE UNIV,DEPT BIOL SCI,NORMAL,IL 61790

来源：

TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 02期

关键词：

D O I：

10.1007/BF00161888

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(II) complexes of 6-methyl-2-formylpyridine thiosemicarbazone, and its 4N-methyl-, 4N-ethyl-, 4N-phenyl-, 4N-dimethyl-, 4N-diethyl-, 4N-dipropyl-, 3-pyrrolidinyl, 3-piperidinyl- and 3-hexamethyleneiminylthiosemicarbazone derivatives were prepared and characterized. I.r., electronic and e.s.r. spectra of the complexes, as well as H-1 and C-13 n.m.r. spectra of the thiosemicarbazones, were obtained. The thiosemicarbazones and their copper(II) complexes show either modest or no growth inhibitory activity against Aspergillus niger, but the 4N-dialkyl- and 3-azacyclo-derivatives exhibit considerable activity against Paecilomyces variotii.

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页码：195 / 200

页数：6

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共 31 条

[1] SULFUR LIGAND METAL-COMPLEXES .15. SULFUR NITROGEN DONOR LIGAND COMPLEXES OF COPPER [J].

AINSCOUGH, EW ;

BRODIE, AM ;

LARSEN, NG .

INORGANICA CHIMICA ACTA-ARTICLES, 1982, 60 (JUN) :25-34

[2] SOME PROPERTIES OF COPPER AND ZINC-COMPLEXES OF 2-FORMYLPYRIDINE THIOSEMICARBAZONE [J].

ANTHOLINE, WE ;

KNIGHT, JM ;

PETERING, DH .

INORGANIC CHEMISTRY, 1977, 16 (03) :569-574

[3] COPPER-COMPLEXES OF PYRIDINE 2-ALDEHYDE AND 2-ACETYLPYRIDINE THIOSEMICARBAZONES [J].

BELL, CF ;

LOTT, KAK ;

HEARN, N .

POLYHEDRON, 1987, 6 (01) :39-44

[4] SPECTROSCOPIC STUDIES OF METAL-COMPLEXES CONTAINING PI-DELOCALIZED SULFUR LIGANDS - THE PRERESONANCE RAMAN-SPECTRA OF THE ANTITUMOR AGENT 2-FORMYLPYRIDINE THIOSEMICARBAZONE AND ITS CU(II) AND ZN(II) COMPLEXES [J].

BERALDO, H ;

TOSI, L .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1986, 125 (03) :173-182

[5] COMPLEXES OF COBALT(II), NICKEL(II) AND COPPER(II) WITH 4-AMINO-3,5-DIMETHYLISOXAZOLE [J].

BIDDAU, M ;

MASSACESI, M ;

PINNA, R ;

PONTICELLI, G .

TRANSITION METAL CHEMISTRY, 1978, 3 (03) :153-156

[6] SYNTHETIC, SPECTROSCOPIC, AND X-RAY CRYSTALLOGRAPHIC STUDIES ON BINUCLEAR COPPER(II) COMPLEXES WITH A TRIDENTATE NNS-BONDING 2-FORMYLPYRIDINE THIOSEMICARBAZONE LIGAND - THE CHARACTERIZATION OF BOTH NEUTRAL AND DEPROTONATED COORDINATED LIGAND STRUCTURE [J].

BINGHAM, AG ;

BOGGE, H ;

MULLER, A ;

AINSCOUGH, EW ;

BRODIE, AM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (03) :493-499

[7] METAL-ION BINDING-SITES COMPOSED OF MULTIPLE NITROGENOUS HETEROCYCLES - SYNTHESIS AND SPECTRAL AND STRUCTURAL STUDY OF BIS(2,2',2''-TRIPYRIDYLAMINE)COPPER(II) BIS(TRIFLUOROMETHANESULFONATE) AND ITS BIS(ACETONITRILE) ADDUCT [J].

DEDERT, PL ;

THOMPSON, JS ;

IBERS, JA ;

MARKS, TJ .

INORGANIC CHEMISTRY, 1982, 21 (03) :969-977

[8] FLUORENONE HYDRAZINE-S-BENZYLDITHIOCARBAZATE TRANSITION-METAL COMPLEXES [J].

ELSONBATI, AZ ;

MABROUK, EM ;

MEGAHED, HE .

TRANSITION METAL CHEMISTRY, 1991, 16 (02) :280-284

[9] SYNTHESIS, SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION OF CHLOROBIS(METHYL PYRUVATE THIOSEMICARBAZONE)COPPER(I) AND CHLOROBIS(TRIPHENYLPHOSPHINE)(METHYL PYRUVATE THIOSEMICARBAZONE)COPPER(I) TOLUENE SOLVATE (2/1) [J].

FERRARI, MB ;

FAVA, GG ;

LANFRANCHI, M ;

PELIZZI, C ;

TARASCONI, P .

INORGANICA CHIMICA ACTA, 1991, 181 (02) :253-262

[10] On some amide derivatives of thio carbon glycol acids; [J].

Holmberg, B ;

Psilanderhielm, B .

JOURNAL FUR PRAKTISCHE CHEMIE-LEIPZIG, 1910, 82 (10) :440-450

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