NEW STRUCTURAL PARAMETERS FOR CARBON - COMPREHENSIVE CRYSTALLIZATION INDEX AND CAVITY INDEX

被引：25

作者：

FUJIMOTO, H ^{[1
]}

TOKUMITSU, K ^{[1
]}

MABUCHI, A ^{[1
]}

KASUH, T ^{[1
]}

SHIRAISHI, M ^{[1
]}

机构：

[1] NATL INST RESOURCES ENVIRONM,TSUKUBA,IBARAKI 305,JAPAN

来源：

CARBON | 1994年 / 32卷 / 07期

关键词：

CAVITY; LOGISTIC CURVE; CRYSTALLITE; CARBONIZATION;

D O I：

10.1016/0008-6223(94)90109-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New structural parameters designated 'comprehensive crystallization index' (CCI) and 'cavity index' have been mathematically derived from the density, lattice constant, and crystallite size of carbon materials by assuming a model of crystallite. These indices calculated for several carbon materials were plotted as a function of the heat-treatment temperature (HTT). Thereby, it is demonstrated that CCI well represents the crystal growth with increasing HTT in the form of a logistic curve.

引用

页码：1249 / 1252

页数：4

共 10 条

[1] X-RAY DIFFRACTION DATA FOR LARGE AROMATIC MOLECULES [J].

DIAMOND, R .

ACTA CRYSTALLOGRAPHICA, 1957, 10 (05) :359-364

[2] A LEAST-SQUARES ANALYSIS OF THE DIFFUSE X-RAY SCATTERING FROM CARBONS [J].

DIAMOND, R .

ACTA CRYSTALLOGRAPHICA, 1958, 11 (03) :129-138

[3] X-RAY STUDIES OF SOME CARBONIZED COALS [J].

DIAMOND, R .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1960, 252 (1008) :193-223

[4]

DIAMOND R, 1956, THESIS U CAMBRIDGE

[5]

DIAMOND R, 1957, 3RD P C CARB NEW YOR, P367

[6] PORE STRUCTURE OF PHENOL-FORMALDEHYDE RESIN CARBONS [J].

FURUTA, T ;

SANADA, Y ;

HONDA, H .

CARBON, 1969, 7 (04) :510-&

[7]

HONDA H, 1955, J CHEM SOC JAPAN PUR, V76, P148

[8]

INAGAKI M, 1963, TANSO, V36, P139

[9] AN X-RAY DIFFRACTION STUDY OF PHENOL-FORMALDEHYDE RESIN CARBONS [J].

KOBAYASHI, K ;

SUGAWARA, S ;

TOYODA, S ;

HONDA, H .

CARBON, 1968, 6 (03) :359-+

[10]

SHIRAISHI M, 1972, NIPPON KAGAKUKAI SHI, V6, P1135

← 1 →