The HSAB principle - More quantitative aspects

被引：314

作者：

Pearson, RG

机构：

[1] Chemistry Department, University of California, Santa Barbara

来源：

INORGANICA CHIMICA ACTA | 1995年 / 240卷 / 1-2期

关键词：

HSAB principle; acids and bases;

D O I：

10.1016/0020-1693(95)04648-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The HSAB Principle is reviewed, with special emphasis on common misconceptions of its meaning. The most quantitative way to use it is discussed, along with an analysis of why it sometimes seems to fail. Recent developments in the concept of chemical hardness are also reviewed. It is concluded that these have not yet helped much in estimating bond energies, but that there is hope for the future.

引用

收藏

页码：93 / 98

页数：6

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