HIGH DIASTEREOFACIAL DIFFERENTIATION IN OSMIUM TETRAOXIDE CATALYZED DIHYDROXYLATION OF ACYCLIC BIS-ALLYLIC COMPOUNDS

被引：61

作者：

SAITO, S

MORIKAWA, Y

MORIWAKE, T

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Okayama University, Tsushima, Okayama

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 20期

关键词：

D O I：

10.1021/jo00307a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

:Bisallylic compounds such as diethyl (4S, 5S)-4,5-bis ((tert-butyldimethylsilyl)oxy) -2,6-octadienedioate (1a) exhibit very high diastereoselection in osmium tetraoxide catalyzed dihydroxylation; a particular ground-state conformation is proposed to be responsible. © 1990, American Chemical Society. All rights reserved.

引用

页码：5424 / 5426

页数：3

共 25 条

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