SYNTHESIS, STRUCTURE, AND MAGNETISM OF BA2VO(PO4)2.H2O, A NEW BARIUM VANADIUM(IV) PHOSPHATE HYDRATE

被引：29

作者：

HARRISON, WTA ^{[1
]}

LIM, SC ^{[1
]}

VAUGHEY, JT ^{[1
]}

JACOBSON, AJ ^{[1
]}

GOSHORN, DP ^{[1
]}

JOHNSON, JW ^{[1
]}

机构：

[1] EXXON RES & ENGN CO,CORP RES LABS,ANNANDALE,NJ 08801

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1994年 / 113卷 / 02期

关键词：

D O I：

10.1006/jssc.1994.1394

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal synthesis, which requires the presence of zinc nitrate and tetraethylammonium hydroxide, and the single-crystal structure of Ba2VO(PO4)2.H2O are described. The Ba2VO(PO4)2.H2O structure is built up from discrete, infinite VO(PO4)2.H2O chains, built up from VO6 and PO4 moieties, sparated by 11-coordinate Ba2+ cations. Magnetic susceptibility data for Ba2VO(PO4)2.H2O are consistent with V(IV) and show magnetic ordering below approximately 10 K and paramagnetic behavior from approximately 15-300 K. Crystal data: Ba2VO(PO4)2.H2O, M(r) = 549.56, monoclinic, space group C2/m (No. 12), a = 12.420(3) angstrom, b = 5.219(2) angstrom, c = 6.941(2) angstrom, beta = 104.52(2)-degrees, V = 435.55 angstrom-3, Z = 2, R = 2.14%, R(W) = 2.45% (879 reflections with I > 3 sigma(I)). (C) 1994 Academic Press, Inc.

引用

页码：444 / 447

页数：4

共 16 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2]

BENHAMADA L, 1991, ACTA CRYSTALLOGR C, V47, P2438

[3] BOND-VALENCE PARAMETERS FOR SOLIDS [J].

BRESE, NE ;

OKEEFFE, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197

[4] HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURES OF BA2FE3H(PO4)2(P2O7)2 AND BA2V3H(PO4)2(P2O7)2 [J].

DVONCOVA, E ;

LII, KH ;

LI, CH ;

CHEN, TM .

JOURNAL OF SOLID STATE CHEMISTRY, 1993, 106 (02) :485-492

[5] BAV2P2O10, A NEW TETRAVALENT VANADIUM PHOSPHATE WITH A TUNNEL STRUCTURE [J].

GRANDIN, A ;

CHARDON, J ;

BOREL, MM ;

LECLAIRE, A ;

RAVEAU, B .

JOURNAL OF SOLID STATE CHEMISTRY, 1992, 99 (02) :297-302

[6]

HARRISON WTA, 1994, IN PRESS J SOLID STA

[7] OCTAHEDRAL TETRAHEDRAL FRAMEWORK SOLIDS OF THE VANADIUM PHOSPHATE SYSTEM - HYDROTHERMAL SYNTHESES AND CRYSTAL-STRUCTURES OF THE VANADIUM(III) PHOSPHATE CS[VIII2(PO4)(HPO4)2(H2O)2] AND OF THE MIXED-VALENCE SPECIES K[(VIVO)VIII(HPO4)3(H2O)2] [J].

HAUSHALTER, RC ;

WANG, ZW ;

THOMPSON, ME ;

ZUBIETA, J .

INORGANIC CHEMISTRY, 1993, 32 (17) :3700-3704

[8] REDOX INTERCALATION REACTIONS OF VOPO4.2H2O WITH MONO-VALENT AND DIVALENT-CATIONS [J].

JACOBSON, AJ ;

JOHNSON, JW ;

BRODY, JF ;

SCANLON, JC ;

LEWANDOWSKI, JT .

INORGANIC CHEMISTRY, 1985, 24 (12) :1782-1787

[9]

JOHNSON CK, 1976, ORNL5138 REP

[10] INCLUSION OF SECONDARY EXTINCTION IN LEAST-SQUARES CALCULATIONS [J].

LARSON, AC .

ACTA CRYSTALLOGRAPHICA, 1967, 23 :664-&

← 1 2 →