INFLUENCE OF TEMPERATURE-GRADIENTS ON VELOCITY PROFILES AND SEPARATION PARAMETERS IN THERMAL FIELD-FLOW FRACTIONATION

被引:67
作者
GUNDERSON, JJ
CALDWELL, KD
GIDDINGS, JC
机构
[1] Univ of Utah, Dep of Chemistry, Salt, Lake City, UT, USA, Univ of Utah, Dep of Chemistry, Salt Lake City, UT, USA
关键词
FLOW OF FLUIDS - Laminar - LIQUIDS;
D O I
10.1080/01496398408060668
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The form of the asymmetrical velocity profile present in thermal field-flow fractionation is investigated. A theoretical treatment of retention and nonequilibrium peak broadening is given for an exponential concentration profile combined with the asymmetrical velocity profile. The different consequences of the symmetrical and asymmetrical velocity profiles are discussed.
引用
收藏
页码:667 / 683
页数:17
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