IR STUDY OF OZONE ADSORPTION ON SIO2

被引：63

作者：

BULANIN, KM

ALEXEEV, AV

BYSTROV, DS

LAVALLEY, JC

TSYGANENKO, AA

机构：

[1] UNIV CAEN,ISMRA,CATALYSE & SPECTROCHIM LAB,CNRS,URA 414,F-14050 CAEN,FRANCE

[2] ST PETERSBURG STATE UNIV,INST PHYS,ST PETERSBURG 198904,RUSSIA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 19期

关键词：

D O I：

10.1021/j100070a026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Adsorption of various isotopic modifications of ozone was performed at 80 K and followed by infrared spectroscopy, on silica activated at 923 K. Hydrogen-bonded species were formed and the surface hydroxyls frequency shift indicated that ozone basicity is close to that of CO. Most of the fundamentals, overtones, and combination bands of adsorbed ozone were detected. Their wavenumbers were close to those observed for ozone dissolved in liquid oxygen or physisorbed on methoxylated silica. Adsorption of (OOO)-O-16-O-18-O-18 indicated that hydrogen bonding occurred via one of the terminal oxygen atoms rather than via the O-3 oxygen central atom.

引用

页码：5100 / 5103

页数：4

共 15 条

[1] Alekseev A.V., 1990, PHOTOCHEMICAL PROCES, P20
[2] INFRARED-SPECTRA OF THE O3--HF AND SO2--HF COMPLEXES IN SOLID ARGON
ANDREWS, L
WITHNALL, R
HUNT, RD
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (01) : 78 - 81
[3] CO INTERACTION WITH THE SURFACE OF THERMALLY ACTIVATED CAO AND MGO
BABAEVA, MA
BYSTROV, DS
KOVALGIN, AY
TSYGANENKO, AA
[J]. JOURNAL OF CATALYSIS, 1990, 123 (02) : 396 - 416
[4] ANALYSIS OF THE NU-1+NU-2+NU-3 BAND OF O-3
BARBE, A
SECROUN, C
GOLDMAN, A
GILLIS, JR
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1983, 100 (02) : 377 - 381
[5] INFRARED-SPECTRA OF 16O3 AND 18O3 - DARLING AND DENNISON RESONANCE AND ANHARMONIC POTENTIAL FUNCTION OF OZONE
BARBE, A
SECROUN, C
JOUVE, P
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1974, 49 (02) : 171 - 182
[6] BARBE A, 1969, CR ACAD SCI B PHYS, V268, P1723
[7] VIBRATIONAL FREQUENCIES OF OZONE - A MULTICONFIGURATIONAL APPROACH
BOROWSKI, P
ANDERSSON, K
MALMQVIST, PA
ROOS, BO
[J]. JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (08) : 5568 - 5577
[8] THE UPSILON-1 AND UPSILON-3 BANDS OF (O3)-O-3 AND (OOO)-O-18-O-16-O-18 - LINE POSITIONS AND INTENSITIES
FLAUD, JM
CAMYPEYRET, C
DEVI, VM
RINSLAND, CP
SMITH, MAH
[J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1987, 122 (01) : 221 - 228
[9] INTERACTION OF OZONE WITH GAMMA-AL2O3 SURFACE
KLIMOVSKII, AO
BAVIN, AV
TKALICH, VS
LISACHENKO, AA
[J]. REACTION KINETICS AND CATALYSIS LETTERS, 1983, 23 (1-2): : 95 - 98
[10] OZONE DECOMPOSITION ON ALPHA-FE2O3 CATALYST
MEHANDJIEV, D
NAIDENOV, A
[J]. OZONE-SCIENCE & ENGINEERING, 1992, 14 (04) : 277 - 282

← 1 2 →