THE MECHANISM OF NITRATION OF 2,4,6-TRIALKYLPHENOLS BY NITROGEN-DIOXIDE IN SOLUTION

被引：11

作者：

COOMBES, RG

DIGGLE, AW

KEMPSELL, SP

机构：

[1] SHELL RES LTD,THORNTON RES CTR,CHESTER CH1 3SH,CHESHIRE,ENGLAND

[2] CITY UNIV LONDON,DEPT CHEM,LONDON EC1V 0HB,ENGLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)61384-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The apparent rate of reaction of 2,4,6-trialkylphenols with nitrogen dioxide in solution is that of a 6-nitrocyclohexa-2,4-dien-1-one to 4-nitrocyclohexa-2,5-dien-1-one isomerisation unless the 2- and 6-alkyl groups are sufficiently bulky when the rare limiting stage may involve reaction between the appropriate phenoxy radical and NO2.

引用

页码：8557 / 8560

页数：4

共 11 条

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