A FOURIER TRANSFORM-ION CYCLOTRON-RESONANCE STUDY OF THE REACTIVITY OF IONIZED VINYLALCOHOL WITH SELECTED UNSATURATED-COMPOUNDS

被引：29

作者：

BERRUYER, F ^{[1
]}

BOUCHOUX, G ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCMR,F-91128 PALAISEAU,FRANCE

来源：

RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 1990年 / 4卷 / 11期

关键词：

D O I：

10.1002/rcm.1290041105

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Reactions between CX2CXOX+· (X  H or D) and alkenes, an alkyne, benzene, aldehydes and ketones have been studied by Fourier transform mass spectrometry. Most of the neutral species undergo charge exchange or proton transfer reactions with high rates; l‐alkenes lead to slower cycloaddition reactions. The thermochemistry and considerations on the reaction specificities are discussed. Copyright © 1990 John Wiley & Sons Limited

引用

页码：476 / 480

页数：5

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