ELECTROCHEMICAL PROPERTIES OF DIFENZOQUAT HERBICIDE (1,2-DIMETHYL-3,5-DIPHENYL-PYRAZOLIUM)

被引:7
作者
POSPISIL, L
COLOMBINI, MP
FUOCO, R
STRELETS, VV
机构
[1] UNIV PISA, DIPARTMENTO CHIM, I-56100 PISA, ITALY
[2] CNR, IST CHIM ANALIT STRUMENTALE, I-56100 PISA, ITALY
[3] ACAD SCI USSR, INST CHEM PHYS, CHERNOGOLOVKA 142432, USSR
关键词
D O I
10.1016/0022-0728(91)85260-V
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The electrochemical characterization of 1,2-dimethyl-3,5-diphenyl-pyrazolium cation (difenzoquat) in water, methanol and acetonitrile is reported. Two-electron reduction in the range -1.27 to -1.52 V is coupled with a chemical step. The suggested mechanism includes dimerization of an intermediate and substituted pyrazoline as the product. The interpretation is based on dc polarography, cyclic voltammetry and UV spectra of the products of electrolysis.
引用
收藏
页码:169 / 178
页数:10
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