SUBSTRATE-SPECIFIC CATALYSIS BY ION-PAIRS

被引：30

作者：

SMITH, PJ ^{[1
]}

KIM, EI ^{[1
]}

WILCOX, CS ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 11期

关键词：

D O I：

10.1002/anie.199316481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rate accelerations up to 400‐fold are observed for the reaction of amine 1 with 1‐chloro‐2,4‐dinitrobenzene in CHCl3 to give 3 when simple ion pairs like tetrabutylammonium tosylate (or benzylate) are added. The exact reaction mechanism is not yet known. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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页码：1648 / 1650

页数：3

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