EXCHANGE REACTIONS OF TRIS(DIMETHYLAMINO)PHOSPHINE AND ARSINE WITH PERFLUOROALKYL IODIDES

被引：15

作者：

ANG, HG

MANOUSSA.G

ELNIGUMI, YO

机构：

[1] University Chemical Laboratory, Cambridge, Lensfield Road

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1968年 / 30卷 / 07期

关键词：

D O I：

10.1016/0022-1902(68)80343-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris(dimethylamino)phosphine reacts with trifluoromethyl- and iso-heptafluoropropyl iodides to give (Me2N)2PRf (Rf = CF3 and iso-C3F7) and tetrakis(dimethylamino)phosphonium iodide. The corresponding reaction between trifluoromethyl iodide and tris(dimethylamino)-arsine gives bis(dimethylamino)trifluoromethylarsine and tetrakis(dimethylamino)arsonium iodide. 1H NMR data are recorded. © 1968.

引用

页码：1715 / &