PERTURBATIONS IN THE C3-PI(UPSILON'=1) STATE OF ALN STUDIED BY LASER SPECTROSCOPY

被引：12

作者：

EBBEN, M

TERMEULEN, JJ

机构：

[1] Molecular and Laser Physics, Katholieke Universiteit Nijmegen, 6525 ED Nijmegen, Toernooiveld

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 177卷 / 03期

关键词：

D O I：

10.1016/0009-2614(91)85021-N

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

We report the LIF spectrum of the C3-PI (upsilon' = 1) <--X3-PI(upsilon" = 0) transition in the AlN molecule. Laser vaporization in combination with supersonic expansion and laser-induced fluorescence are used to produce and detect the AlN molecules. The molecular constants and electronic lifetimes of the C state are determined. Predissociation and an accidental perturbation are discussed and compared to an ab initio potential calculation of the electronic states.

引用

页码：229 / 234

页数：6

共 7 条

[1]

LASER EVAPORATION AS A SOURCE OF SMALL FREE-RADICALS [J].