SYNTHESIS OF PENTACOORDINATED TETRAALKYLAMMONIUM AND TETRAALKYLPHOSPHONIUM DIFLUOROSILICATES

被引：12

作者：

ALBANESE, D ^{[1
]}

LANDINI, D ^{[1
]}

PENSO, M ^{[1
]}

机构：

[1] UNIV MILAN,DIPARTIMENTO CHIM ORGAN & IND,I-20133 MILAN,ITALY

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 48期

关键词：

D O I：

10.1016/0040-4039(95)01841-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several quaternary onium difluorosilicates 3, R(2)(1)R(2)SiF(2)(-) Q(+) (Q = R(3)(3)R(4)N(+), R(3)(3)R(4)P(+)), have been prepared by reaction of a trisubstitued silane I, R(2)(1)R(2)SiH, and an onium hydrogendifluoride 2, Q(+) HF2-, in benzene. The products 3 are isolated in very good yields (92-98%) and purity (> 99%).

引用

页码：8865 / 8866

页数：2

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