THE IMPEDANCE OF AN ELECTRODE FOR THE SITUATION WHERE THERE IS A DISCONTINUOUS CHANGE OF THE ELECTRODE CONDITION WITH POTENTIAL DUE TO THE FORMATION OF A 2-DIMENSIONAL CONDENSED-PHASE

被引：12

作者：

ARMSTRONG, RD

机构：

[1] Chemistry Department, University of Newcastle upon Tyne, Newcastle upon Tyne

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1994年 / 372卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(93)03253-L

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

It is shown that a recent model which has been developed to explain the impedance of an electrode for the situation where there is a discontinuous change of the electrode condition with potential due to the formation of a two-dimensional condensed phase is flawed in that (i) its assumptions run counter to thermodynamic requirements and standard nucleation theory and (ii) it takes no account of the requirements for a well-defined small signal electrode impedance.

引用

页码：27 / 32

页数：6

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