DESIGN AND ARCHITECTURE OF MACROMOLECULAR STRUCTURES

被引：5

作者：

VOGL, O

KRATKY, C

SIMONSICK, WJ

XI, F

HATADA, K

机构：

[1] GRAZ UNIV,INST PHYS CHEM,A-8010 GRAZ,AUSTRIA

[2] DUPONT CO,MARSHALL RES & DEV LAB,PHILADELPHIA,PA 19146

[3] CHINESE ACAD SCI,INST CHEM,BEIJING,PEOPLES R CHINA

[4] OSAKA UNIV,FAC ENGN SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1992年 / 53卷

关键词：

D O I：

10.1002/masy.19920530115

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Macromolecules exist in a variety of molecular and supermolecular arrangements. Among these are random coils and regular polymer structures with extended chain, some with lamellar and spherulitic morphology and rigid rod structures. An important macromolecular arrangement is the helical structure. For the control of the synthesis of the perfect helix, the stereochemistry of the oligomerization was studied; the best example for this investigation was found to be the oligomerization of the trihaloacetaldehydes, e.g. fluoral, chloral and bromal.

引用

页码：151 / 162

页数：12

共 39 条

[1] CONFORMATIONAL RIGIDITY OF POLYCHLORAL - EFFECT OF BULKY SUBSTITUENTS ON THE POLYMERIZATION MECHANISM [J].