A SHORT FORMAL SYNTHESIS OF (-)-SERRICORNINE

被引：11

作者：

PILLI, RA

DEANDRADE, CKZ

机构：

[1] Universidade Estadual de Campinas, Instituto de Quimica, 13081-970 Campinas,SP

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 02期

关键词：

D O I：

10.1080/00397919408013822

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A short and efficient formal synthesis of serricornine (1), the sex pheromone of Lasioderma serricorne F., is described. The homochiral aldol 5 is straightforwardly converted to tosylate 9 to give homochiral lactone 2a (6 steps, 22% overall yield from oxazolidinone 4), a known precursor of (-)-1.

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页码：233 / 241

页数：9

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