THE ASYMMETRIC KHARASCH REACTION - CATALYTIC ENANTIOSELECTIVE ALLYLIC ACYLOXYLATION OF OLEFINS WITH CHIRAL COPPER(I) COMPLEXES AND TERT-BUTYL PERBENZOATE

被引：159

作者：

ANDRUS, MB

ARGADE, AB

CHEN, X

PAMMENT, MG

机构：

[1] Purdue University, West Lafayette, IN 47907

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 17期

关键词：

D O I：

10.1016/0040-4039(95)00444-H

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Olefins were treated with tert-butyl perbenzoate in the presence of chiral copper(I) triflate bisoxazoline complexes to give non-racemic allyl benzoates as products. The yields range from 34 to 62% and the enantiomeric excesses from 30 to 81%. A model for the selectivity is proposed.

引用

页码：2945 / 2948

页数：4

共 26 条

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