2 OPTICALLY-ACTIVE LUTEOCHROMES - PREPARATION, SPECTRA, AND CHIROPTICAL AND CHROMATOGRAPHIC PROPERTIES

被引：6

作者：

ACEMOGLU, M ^{[1
]}

EUGSTER, CH ^{[1
]}

机构：

[1] UNIV ZURICH, INST ORGAN CHEM, WINTERTHURERSTR 190, CH-8057 ZURICH, SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1984年 / 67卷 / 08期

关键词：

D O I：

10.1002/hlca.19840670826

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective rearrangement of (5R,6S,5''R,6''S)-5,6:5'',6''-diepoxy-5,6,5'',6''-tetrahydro-.beta.,.beta.-carotene with the aid of an ethereal solution of malonic acid leads to the mixture of the C(8'')-epimeric luteochromes. HPLC [high performance liquid chromatography] separation gave the pure isomers. This is the 1st report on the preparation of optically active luteochromes.

引用

页码：2226 / 2230

页数：5

共 13 条

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[9] SEPARATION AND ABSOLUTE-CONFIGURATION OF THE C(8)-EPIMERIC (ALL-E)-NEOCHROMES (TROLLICHROMES) AND DINOCHROMES
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[10] ABSOLUTE-CONFIGURATION OF ANTHERAXANTHIN, CIS-ANTHERAXANTHIN AND OF THE STEREOISOMERIC MUTATOXANTHINS
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