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LINEAR FREE-ENERGY RELATIONSHIPS FOR C1-OXYGENATE DECOMPOSITION ON TRANSITION-METAL SURFACES

被引：70
作者：
BARTEAU, MA
机构：
[1] Center for Catalytic Science and Technology, Department of Chemical Engineering, University of Delaware, Newark, 19716, DE
来源：
CATALYSIS LETTERS | 1991年 / 8卷 / 2-4期
关键词：
TRANSITION METAL CATALYSTS; FORMIC ACID; METHANOL; LINEAR FREE ENERGY RELATIONSHIPS;
D O I：
10.1007/BF00764114
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Linear free energy relationships for the decomposition of formate and methoxide intermediates on metal surfaces have been developed. These demonstrate that Group VIII and Group IB metals do not obey the same correlations. Implications of these observations include the potential for misinterpretation of classical Balandin "volcano" plots.
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页码：175 / 184
页数：10
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