PHOTOGENERATION OF IONS VIA DELOCALIZED CHARGE-TRANSFER STATES .1. XE2H+ AND XE2D+ IN SOLID XE

被引：118

作者：

KUNTTU, H ^{[1
]}

SEETULA, J ^{[1
]}

RASANEN, M ^{[1
]}

APKARIAN, VA ^{[1
]}

机构：

[1] UNIV CALIF IRVINE,INST SURFACE & INTERFACE SCI,DEPT CHEM,IRVINE,CA 92717

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 96卷 / 08期

关键词：

D O I：

10.1063/1.462687

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Delocalized charge-transfer excitations in solid xenon multiply doped with atomic halogens (I, Br, Cl) and hydrogen are demonstrated to lead to charge separation by trapping of the positive charge. As evidence of such a concept we present the first vibrational spectra of Xe2H+ and Xe2D+, which are believed to be vibrationally bound ions.

引用

页码：5630 / 5635

页数：6

共 30 条

[1] REACTIONS OF HE2+, NE2+, AR2+, AND RARE-GAS HYDRIDE IONS WITH HYDROGEN AT 200 DEGREES K
ADAMS, NG
BOHME, DK
FERGUSON, EE
[J]. JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (10) : 5101 - &
[2] SPECTROSCOPY OF MOLECULAR-IONS IN NOBLE-GAS MATRICES
ANDREWS, L
[J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1979, 30 : 79 - 101
[3] MATRIX-ISOLATION INVESTIGATION OF THE HYDROGEN BIHALIDE ANIONS
AULT, BS
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1982, 15 (04) : 103 - 109
[4] BONYBEY VE, 1972, J CHEM PHYS, V56, P3832
[5] ISOTOPE AND POTENTIAL-ENERGY SURFACE EFFECTS IN VIBRATIONAL BONDING
CLARY, DC
CONNOR, JNL
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (13) : 2758 - 2764
[6] LOW-TEMPERATURE PHOTOLYSIS OF HYDROCARBONS IN SOLID XENON - EVIDENCE FOR METASTABLE XENH
CREUZBURG, M
KOCH, F
WITTL, F
[J]. CHEMICAL PHYSICS LETTERS, 1989, 156 (04) : 387 - 391
[7] HYDROGEN CENTERS IN SOLID NOBLE-GASES
CREUZBURG, M
WITTL, F
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1990, 222 (1-2) : 127 - 140
[8] ENERGY-STORAGE AND THERMO-LUMINESCENCE IN HALOGEN DOPED SOLID XENON .3. PHOTODYNAMICS OF CHARGE SEPARATION, SELF-TRAPPING, AND ION HOLE RECOMBINATION
FAJARDO, ME
APKARIAN, VA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (07) : 4124 - 4136
[9] CHARGE-TRANSFER PHOTODYNAMICS IN HALOGEN DOPED XENON MATRICES .2. PHOTOINDUCED HARPOONING AND THE DELOCALIZED CHARGE-TRANSFER STATES OF SOLID XENON HALIDES (F, CL, BR, I)
FAJARDO, ME
APKARIAN, VA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (07) : 4102 - 4123
[10] COOPERATIVE PHOTOABSORPTION INDUCED CHARGE-TRANSFER REACTION DYNAMICS IN RARE-GAS SOLIDS .1. PHOTODYNAMICS OF LOCALIZED XENON CHLORIDE EXCIPLEXES
FAJARDO, ME
APKARIAN, VA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (10) : 5660 - 5681

← 1 2 3 →