2 ISOMERS OF SF5-CENTER-DOT AND SF5+ - STRUCTURES AND ENERGETICS

被引：18

作者：

BECKER, H

HRUSAK, J

SCHWARZ, H

BOHME, DK

机构：

[1] YORK UNIV,DEPT CHEM,N YORK M3J 1P3,ON,CANADA

[2] YORK UNIV,CTR RES EARTH & SPACE SCI,N YORK M3J 1P3,ON,CANADA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 02期

关键词：

D O I：

10.1063/1.466603

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The apparently conflicting results for the ionization energy of SF50 and the standard enthalpy of formation of SF5+ reported over the last 25 years have been reinterpreted and brought into line in terms of the existence of square pyramidal (C-4v) and trigonal bipyramidal (D-3h) isomers of SF50 and SF5+. New experimental results and theoretical calculations are reported which are consistent with this interpretation. Values are recommended for the ionization energy and standard enthalpies of formation for the two isomers of SF50 and SF5+.

引用

页码：1759 / 1760

页数：2

共 14 条

[1] ION-MOLECULE REACTIONS OF SF6 - DETERMINATION OF IP(SF5), AP(SF5+-SF6), AND D(SF5-F) [J].