A STEREOSELECTIVE AND PREPARATIVE ENTRY TO 1,2-ANHYDROSUGARS THROUGH OXIDATION OF GLYCALS WITH PERFLUORO-CIS-2,3-DIALKYLOXAZIRIDINES

被引：21

作者：

CAVICCHIOLI, M

MELE, A

MONTANARI, V

RESNATI, G

机构：

[1] POLITECN MILAN, CNR, CTR SUDIO SOSTANZE ORGAN NAT, I-20131 MILAN, ITALY

[2] POLITECN MILAN, DIPARTIMENTO CHIM, I-20131 MILAN, ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 08期

关键词：

D O I：

10.1039/c39950000901

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Perfluoro-cis-2,3-dialkyloxaziridines 1 perform the direct epoxidation of glycals 2 to give cleanly corresponding 1,2-anhydrosugars 3 with medium to complete diastereoselection; elaboration of these glycals to glycosyl fluorides and lipid conjugates is also reported.

引用

页码：901 / 902

页数：2