SYNTHESIS AND REACTIVITY OF ALLYL SAMARIUM COMPLEXES

被引：25

作者：

COLLIN, J ^{[1
]}

BIED, C ^{[1
]}

KAGAN, HB ^{[1
]}

机构：

[1] UNIV PARIS 11,INST CHIM MOLEC ORSAY,CNRS,SYNTH ASYMETR LAB,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 05期

关键词：

D O I：

10.1016/S0040-4039(00)74845-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allyl chlorides react with SmCp2 to afford an allyl samarium intermediate, the eta-3-allyl structure of which has been tentatively assigned upon its reactivity with ketones. Synthesis of beta,gamma-unsaturated ketones have been also performed by reacting allyl samarium compounds with acid chlorides.

引用

页码：629 / 630

页数：2

共 16 条

[1]

BARBOT F, 1975, TETRAHEDRON LETT, P3829

[2] REVERSIBLE GRIGNARD AND ORGANOLITHIUM REACTIONS [J].

BENKESER, RA ;

SIKLOSI, MP ;

MOZDZEN, EC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (07) :2134-2139

[3] ORGANOALKALI COMPOUNDS BY RADICAL-ANION INDUCED REDUCTIVE METALATION OF PHENYL THIOETHERS [J].

COHEN, T ;

BHUPATHY, M .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (04) :152-161

[4] BENZYLSAMARIUM COMPLEXES AND THEIR REACTIVITY [J].

COLLIN, J ;

NAMY, JL ;

BIED, C ;

KAGAN, HB .

INORGANICA CHIMICA ACTA, 1987, 140 (1-2) :29-30

[5] REACTIVITY OF (C5ME5)2SM AND RELATED SPECIES WITH ALKENES - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A SERIES OF ORGANOSAMARIUM ALLYL COMPLEXES [J].

EVANS, WJ ;

ULIBARRI, TA ;

ZILLER, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (06) :2314-2324

[6] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF BIS(PENTAMETHYLCYCLOPENTADIENYL) LANTHANIDE AND YTTRIUM HALIDE-COMPLEXES [J].

EVANS, WJ ;

GRATE, JW ;

LEVAN, KR ;

BLOOM, I ;

PETERSON, TT ;

DOEDENS, RJ ;

ZHANG, HM ;

ATWOOD, JL .

INORGANIC CHEMISTRY, 1986, 25 (20) :3614-3619

[7] ORGANOLANTHANIDE AND ORGANOACTINIDE OXIDATIVE ADDITIONS EXHIBITING ENHANCED REACTIVITY .4. PRODUCTS, STOICHIOMETRY, AND PRELIMINARY KINETIC-STUDIES OF THE REACTION OF (C5ME5)2SMII.OET2 AND (C5ME5)2EUII.OET2 WITH ALKYL AND ARYL HALIDES - EVIDENCE FOR THE IMPORTANCE OF ELECTRON-TRANSFER IN ATOM-ABSTRACTION OXIDATIVE ADDITIONS [J].

FINKE, RG ;

KEENAN, SR ;

SCHIRALDI, DA ;

WATSON, PL .

ORGANOMETALLICS, 1987, 6 (06) :1356-1358

[8] PI-ALLYL LANTHANOID ATE COMPLEX AS A NEW HIGHLY 1,2-REGIOSELECTIVE ALLYL TRANSFER AGENT FOR ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS [J].

FUKUZAWA, S ;

SATO, K ;

FUJINAMI, T ;

SAKAI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (13) :939-940

[9] DIVALENT LANTHANIDE DERIVATIVES IN ORGANIC-SYNTHESIS .1. MILD PREPARATION OF SMI2 AND YBI2 AND THEIR USE AS REDUCING OR COUPLING AGENTS [J].

GIRARD, P ;

NAMY, JL ;

KAGAN, HB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (08) :2693-2698

[10] HIGHLY REACTIVE ORGANOLANTHANIDES - SYSTEMATIC ROUTES TO AND OLEFIN CHEMISTRY OF EARLY AND LATE BIS(PENTAMETHYLCYCLOPENTADIENYL) 4F HYDROCARBYL AND HYDRIDE COMPLEXES [J].

JESKE, G ;

LAUKE, H ;

MAUERMANN, H ;

SWEPSTON, PN ;

SCHUMANN, H ;

MARKS, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) :8091-8103

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