QUANTITATIVE CORRELATION OF THE PARAMETERS LOG KAPPA-W' AND -S IN THE RETENTION EQUATION IN REVERSED-PHASE HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHIC AND SOLVATOCHROMIC PARAMETERS

被引：27

作者：

ZOU, HF

ZHANG, YK

LU, PC

机构：

[1] Dalian Chromatographic R and D Centre of China, Dalian Institute of Chemical Physics, Academia Sinica, Dalian

来源：

JOURNAL OF CHROMATOGRAPHY | 1990年 / 522卷

关键词：

D O I：

10.1016/0021-9673(90)85176-V

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Multi-variable regression analysis between log k'w and - S inthe retention equation log k′ = log k′w - Sφ{symbol} and solvatochromic parameters was carried out with three kinds of mobile phase and the statistical significance strongly supported the following equations: {A figure is presented}. These equations indicate that the forces involved in the separation mechanism in reversed-phase liquid chromatography have a mutual nature. © 1990.

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页码：49 / 55

页数：7

相关论文

共 16 条

[1] THE USE OF CHARACTERISTIC VOLUMES TO MEASURE CAVITY TERMS IN REVERSED PHASE LIQUID-CHROMATOGRAPHY [J].

ABRAHAM, MH ;

MCGOWAN, JC .

CHROMATOGRAPHIA, 1987, 23 (04) :243-246

[2]

ABRAHAM MH, 1986, CHEM BRIT, V75, P629

[3] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[4] QUANTITATIVE STRUCTURE-ACTIVITY-RELATIONSHIPS FOR HERBICIDES - REVERSED-PHASE LIQUID-CHROMATOGRAPHIC RETENTION PARAMETER, LOG KW, VERSUS LIQUID-LIQUID PARTITION-COEFFICIENT AS A MODEL OF THE HYDROPHOBICITY OF PHENYLUREAS, S-TRIAZINES AND PHENOXYCARBONIC ACID-DERIVATIVES [J].

BRAUMANN, T ;

WEBER, G ;

GRIMME, LH .

JOURNAL OF CHROMATOGRAPHY, 1983, 261 (03) :329-343

[5]

Jandera P., 1981, Advances in Chromatography, V19, P125

[6] CORRELATIONS BETWEEN VANDERWAALS VOLUME AND RETENTION DATA OF ALKYLBENZENE DERIVATIVES IN REVERSED PHASE MICRO HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].

JINNO, K ;

ISHIGAKI, A .

JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY & CHROMATOGRAPHY COMMUNICATIONS, 1982, 5 (12) :668-673

[7]

Kamlet M, 1981, PROGR PHYSICAL ORGAN, V13, P485, DOI DOI 10.1002/9780470171929.CH6

[8] EXPANDED SOLUBILITY PARAMETER TREATMENT FOR CLASSIFICATION AND USE OF CHROMATOGRAPHIC SOLVENTS AND ADSORBENTS - PARAMETERS FOR DISPERSION, DIPOLE AND HYDROGEN-BONDING INTERACTIONS [J].

KARGER, BL ;

SNYDER, LR ;

EON, C .

JOURNAL OF CHROMATOGRAPHY, 1976, 125 (01) :71-88

[9]

KOOPMANS RE, 1985, J CHROMATOGR, V285, P287

[10] SOLUTE-SOLVENT INTERACTIONS IN CHEMISTRY AND BIOLOGY .5. SOME OBSERVATIONS REGARDING DIFFERENT RETENTION PROPERTIES OF HPLC STATIONARY PHASES [J].

PARK, JH ;

CARR, PW ;

ABRAHAM, MH ;

TAFT, RW ;

DOHERTY, RM ;

KAMLET, MJ .

CHROMATOGRAPHIA, 1988, 25 (05) :373-381