TOTAL SYNTHESIS OF CLAVUKERIN-A AND ITS EPIMER

被引：22

作者：

ASAOKA, M

KOSAKA, T

ITAHANA, H

TAKEI, H

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 08期

关键词：

D O I：

10.1246/cl.1991.1295

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enantioselective synthesis of clavukerin A and its epimer was carried out. By the comparison of the spectral data and specific rotations of synthesized and natural ones, two trisnorsesquiterpens isolated from Clavulia and Cespitularia species are confirmed to be identical.

引用

收藏

页码：1295 / 1298

页数：4

相关论文

共 11 条

[1] REACTION OF MIXED CARBOXYLIC ANHYDRIDES WITH GRIGNARD-REAGENTS - USEFUL METHOD FOR PREPARATION OF KETONES [J].

ARAKI, M ;

MUKAIYAM.T .

CHEMISTRY LETTERS, 1974, (07) :663-666

[2] SYNTHESIS OF (R)-(+)-4-BUTYL-2,6-CYCLOHEPTADIENONE, A CONSTITUENT OF MARINE-ALGAE [J].

ASAOKA, M ;

TAKENOUCHI, K ;

TAKEI, H .

CHEMISTRY LETTERS, 1988, (06) :921-922

[3] STUDIES OF AUSTRALIAN SOFT CORALS .30. A NOVEL TRISNORSESQUITERPENE FROM A CESPITULARIA SPECIES AND THE ISOLATION OF GUAIAZULENE FROM A SMALL BLUE ALCYONIUM SPECIES [J].

BOWDEN, BF ;

COLL, JC ;

TAPIOLAS, DM .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1983, 36 (01) :211-214

[4]

DAWBEN WG, 1976, TETRAHEDRON LETT, P2951

[5]

KOBAYASHI M, 1984, CHEM PHARM BULL, V32, P1667

[6]

KOBAYASHI M, 1983, CHEM PHARM BULL, V31, P2160

[7]

KREBS HC, 1986, PROGR CHEM ORGANIC N, V49, P223

[8]

NAKAMURA E, 1986, ORG SYNTH, V66, P43

[9] STEREOCONTROLLED TOTAL SYNTHESIS OF AN ALPHA-METHYLENE GUAIANOLIDE IN THE 4,5-EPOXYOSMITOPSIN FAMILY [J].

POSNER, GH ;

BABIAK, KA ;

LOOMIS, GL ;

FRAZEE, WJ ;

MITTAL, RD ;

KARLE, IL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (25) :7498-7505

[10] GENERATION OF 2-CARBOETHOXYEHTYLZINC IODIDE AND 3-CARBOETHOXYPROPYLZINC IODIDE AND THEIR APPLICATION TO THE SYNTHESIS OF GAMMA-KETO AND DELTA-KETO ESTERS [J].

TAMARU, Y ;

OCHIAI, H ;

NAKAMURA, T ;

TSUBAKI, K ;

YOSHIDA, Z .

TETRAHEDRON LETTERS, 1985, 26 (45) :5559-5562