ETA-ARENE COMPLEXES OF SCANDIUM(0) AND SCANDIUM(II)

被引：46

作者：

CLOKE, FGN ^{[1
]}

KHAN, K ^{[1
]}

PERUTZ, RN ^{[1
]}

机构：

[1] UNIV YORK,DEPT CHEM,YORK YO1 5DD,N YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 19期

关键词：

D O I：

10.1039/c39910001372

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cocondensation of scandium vapour with 1,3,5-tri-tert-butylbenzene affords the first example of a scandium(0) complex, the sandwich compound bis(eta-1,3,5-tri-tert-butylbenzene)scandium; ESR and UV studies also the reveal the presence of a second compound from this reaction, formulated as a similarly unique example of scandium(II) arising from activation of one of the methyl groups of a tert-butyl ring substituent.

引用

页码：1372 / 1373

页数：2

共 6 条

[1] ON THE STABILITY AND BONDING IN BIS(ETA-ARENE)LANTHANIDE COMPLEXES
ANDERSON, DM
CLOKE, FGN
COX, PA
EDELSTEIN, N
GREEN, JC
PANG, T
SAMEH, AA
SHALIMOFF, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (01) : 53 - 55
[2] SYNTHESIS OF BIS(ETA-1,3,5-TRI-T-BUTYLBENZENE) SANDWICH COMPLEXES OF YTTRIUM(0) AND GADOLINIUM(0) - THE X-RAY CRYSTAL-STRUCTURE OF THE 1ST AUTHENTIC LANTHANIDE(0) COMPLEX, [GD(ETA-BUT3C6H3)2]
BRENNAN, JG
CLOKE, FGN
SAMEH, AA
ZALKIN, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (21) : 1668 - 1669
[3] CLOKE FGN, 1989, POLYHEDRON, V8, P1641
[4] BIS(ETA-PENTAMETHYLCYCLOPENTADIENYL) COMPLEXES OF MOLYBDENUM, TUNGSTEN AND RHENIUM VIA METAL VAPOR SYNTHESIS
CLOKE, FGN
DAY, JP
GREEN, JC
MORLEY, CP
SWAIN, AC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, : 789 - 796
[5] SYNTHESIS OF ZEROVALENT BIS(ETA-ARENE) COMPOUNDS OF ZIRCONIUM, HAFNIUM, NIOBIUM, TANTALUM, AND TUNGSTEN USING THE METAL VAPORS
CLOKE, FGN
GREEN, MLH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (09): : 1938 - 1943
[6] ACTIVATION OF SP3 CARBON-HYDROGEN BONDS OF ALKYLBENZENES BY RHENIUM FORMING BINUCLEAR MU-ARYLIDENE DERIVATIVES
CLOKE, FGN
DEROME, AE
GREEN, MLH
OHARE, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (22) : 1312 - 1313

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