SYNTHESIS AND MOLECULAR-STRUCTURE OF [1,3-(ME3SI)2C5H3](ME3SIC5H4)ZRCL2

被引：5

作者：

THIELE, KH ^{[1
]}

BOHME, U ^{[1
]}

PETERS, K ^{[1
]}

PETERS, EM ^{[1
]}

WALZ, L ^{[1
]}

VONSCHNERING, HG ^{[1
]}

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,W-7000 STUTTGART 80,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 04期

关键词：

ZIRCONOCENE COMPLEXES; CRYSTAL STRUCTURE CYCLOPENTADIENYL COMPOUNDS;

D O I：

10.1002/zaac.19936190422

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unsymmetrically substituted zirconocene dichloride was prepared by reaction of trimethylsilylcyclopentadienyl lithium and 1,3-bis(trimethylsilyl)cyclopentadienyl lithium with ZrCl4.2 THE. The molecular structure was determined (P2(1)/a; a = 1357.9, b = 1900.0, c = 1 043.2 pm, beta = 105,16-degrees). The Zr-Cl distance are remarkably short.

引用

页码：771 / 774

页数：4

共 8 条

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