SYNTHESIS AND CHARACTERIZATION OF THIOLATO COMPLEXES WITH 2-COORDINATE IRON(II)

被引：105

作者：

ELLISON, JJ ^{[1
]}

RUHLANDTSENGE, K ^{[1
]}

POWER, PP ^{[1
]}

机构：

[1] UNIV CALIF DAVIS, DEPT CHEM, DAVIS, CA 95616 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 11期

关键词：

D O I：

10.1002/anie.199411781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Coordination number two, ten valence electrons, and highly bent ligands owing to the weak secondary interactions with ortho mesityl substituents—these characteristic features are present in one (shown on the right) of the first two thiolato complexes with a two‐coordinate FeII center. Low coordinate iron centers of this kind bound to sulfur are of particular interest in light of the crystal structure of the FeMo cofactor of nitrogenase. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：1178 / 1180

页数：3

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