NOVEL SYNTHESIS OF ALPHA-STANNYL VINYL ETHERS FROM CATALYTIC AND STOICHIOMETRIC FISCHER CARBENE ANIONS

被引：40

作者：

MCDONALD, FE

SCHULTZ, CC

CHATTERJEE, AK

机构：

[1] Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 08期

关键词：

D O I：

10.1021/om00008a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tributyltin triflate reacts with catalytic molybdenum carbene anion intermediates generated by alkynol cyclization, providing a novel and practical synthesis of alpha-(tributylstannyl)dihydrofurans. Similar reactivity is observed with stoichiometric cyclic and acyclic chromium carbene anions.

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页码：3628 / 3629

页数：2

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