SYNTHESIS AND CHARACTERIZATION OF A WATER-SOLUBLE POLY(PARA-PHENYLENEVINYLENE) DERIVATIVE

被引：114

作者：

SHI, SQ

WUDL, F

机构：

[1] UNIV CALIF SANTA BARBARA,INST POLYMERS & ORGAN SOLIDS,DEPT PHYS,SANTA BARBARA,CA 93106

[2] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

MACROMOLECULES | 1990年 / 23卷 / 08期

关键词：

D O I：

10.1021/ma00210a004

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We report the preparation of a water-soluble poly(p-phenylenevinylene) (PPV) derivative, poly[5-methoxy-2-(3-sulfopropoxy)-l,4-phenylenevinylene], by a conventional precursor polymer approach. The conversion of the precursor polymer into fully conjugated PPV can be carried out in solution and in the solid state. We also describe a novel way to hydrolyze a sulfonyl chloride in the precursor polymer by refluxing with a small amount of DMF in water. Electronic spectroscopy reveals that the as-formed polymer is Brønsted acid doped and that it can be compensated (undoped) with ammonia. © 1990, American Chemical Society. All rights reserved.

引用

页码：2119 / 2124

页数：6

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