ALL-SOLID-STATE ELECTROCHROMIC DEVICE .1. ELECTROPHORETIC DEPOSITION FILM OF PROTON CONDUCTIVE SOLID ELECTROLYTE

被引：10

作者：

KUWABARA, K

SUGIYAMA, K

OHNO, M

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya, 464, Furo-cho

来源：

SOLID STATE IONICS | 1991年 / 44卷 / 3-4期

关键词：

D O I：

10.1016/0167-2738(91)90024-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrophoretic deposition of tin phosphate (SnP) was studied by using ITO glass overcoated with tungsten trioxide thin film as the substrate electrode. The SnP powder was dispersed in acetone to prepare the suspension. The addition effect of ammonium hydroxide to the tin phosphate suspension on the deposition feature was examined to find the best deposition film. The characterization of the deposition films was carried out by XRD, TG, DSC, IR and impedance measurements. The homogeneous and highly adhesive film was obtained on the anode at the concentration ratio [ammonium hydroxide]/[tin phosphate] of 1/30. The film is used as the solid electrolyte for ECD. The electrophoretic deposition mechanism was discussed.

引用

页码：313 / 318

页数：6

共 19 条

[1] MECHANISM OF DIFFUSION AND IONIC TRANSPORT IN CRYSTALLINE INSOLUBLE ACID SALTS OF TETRAVALENT METALS .1. ELECTRICAL CONDUCTANCE OF ZIRCONIUM BIS (MONOHYDROGEN ORTHO-PHOSPHATE) MONOHYDRATE WITH A LAYERED STRUCTURE [J].

ALBERTI, G ;

CASCIOLA, M ;

COSTANTINO, U ;

LEVI, G ;

RICCIARDI, G .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1978, 40 (03) :533-537

[2] RECENT PROGRESS IN FIELD OF SYNTHETIC INORGANIC EXCHANGERS HAVING A LAYERED OR FIBROUS STRUCTURE [J].

ALBERTI, G ;

COSTANTINO, U .

JOURNAL OF CHROMATOGRAPHY, 1974, 102 (DEC31) :5-29

[3] AC CONDUCTIVITY OF ANHYDROUS PELLICULAR ZIRCONIUM-PHOSPHATE IN HYDROGEN FORM [J].

ALBERTI, G ;

CASCIOLA, M ;

COSTANTINO, U ;

LEONARDI, M .

SOLID STATE IONICS, 1984, 14 (04) :289-295

[4] ALPHA-ZIRCONIUM HYDROGENPHOSPHATE, MONOHYDRATE - PREPARATION, CHEMICAL-PROPERTIES AND AC CONDUCTIVITY [J].

ANDERSEN, EK ;

ANDERSEN, IGK ;

MOLLER, CK ;

SIMONSEN, KE ;

SKOU, E .

SOLID STATE IONICS, 1982, 7 (04) :301-306

[5] CRYSTALLOGRAPHY AND STRUCTURE OF ALPHA-ZIRCONIUM BIS(MONOHYDROGEN ORTHOPHOSPHATE) MONOHYDRATE [J].

CLEARFIELD, A ;

SMITH, GD .

INORGANIC CHEMISTRY, 1969, 8 (03) :431-+

[6] OPTICAL AND PHOTOELECTRIC PROPERTIES AND COLOR CENTERS IN THIN-FILMS OF TUNGSTEN OXIDE [J].

DEB, SK .

PHILOSOPHICAL MAGAZINE, 1973, 27 (04) :801-822

[7]

DEB SK, 1990, P S ELECTROCHROMIC M, P3

[8] PRINCIPLES AND OPERATION OF AN ALL SOLID-STATE ELECTROCHROMIC DISPLAY BASED ON A- WO3 [J].

DENEUVILLE, A ;

GERARD, P ;

BILLAT, R .

THIN SOLID FILMS, 1980, 70 (02) :203-223

[9] SOLID-STATE ELECTROCHROMIC DISPLAY [J].

GREEN, M ;

KANG, K .

SOLID STATE IONICS, 1981, 3-4 (AUG) :141-147

[10] SOLID-STATE ELECTROCHROMIC CELL - RBAG4I5/WO3 SYSTEM [J].

GREEN, M ;

RICHMAN, D .

THIN SOLID FILMS, 1974, 24 (02) :S45-S46

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