ELECTROCHEMISTRY AND ELECTROGENERATED CHEMILUMINESCENCE OF FILMS OF THE CONJUGATED POLYMER 4-METHOXY-(2-ETHYLHEXOXYL)-2,5-POLYPHENYLENEVINYLENE

被引：93

作者：

RICHTER, MM ^{[1
]}

FAN, FRF ^{[1
]}

KLAVETTER, F ^{[1
]}

HEEGER, AJ ^{[1
]}

BARD, AJ ^{[1
]}

机构：

[1] UNIAX CORP,SANTA BARBARA,CA 93111

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 226卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(94)00716-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The thin film electrochemistry and electrogenerated chemiluminescence (ECL) of the title compound were obtained on Pt electrodes (CH3CN/0.1 M tetrabutylammonium fluoroborate). Orange luminescence (lambda(max) = 622 nm) was obtained by pulsing the potentials between +0.40 and -2.35 V versus Fc/Fc+ as well as by oxidizing the system in the presence of TPAH (TPAH=tri-n-propylamine), which generates the strongly reducing intermediate TPA., and by reducing the system in the presence of S2O82-, which produces the strongly oxidizing intermediate SO4-..

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页码：115 / 120

页数：6

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