INFLUENCE OF THE SOLVENT ON THE TITANIUM-BETA CATALYZED OXIDATION OF PHENYLETHYLENES WITHOUT CARBON-CARBON DOUBLE-BOND CLEAVAGE

被引：18

作者：

ALVARO, M

CORMA, A

GARCIA, H

VALENCIA, S

机构：

[1] UNIV POLITECN VALENCIA,DEPT QUIM,E-46071 VALENCIA,SPAIN

[2] UNIV POLITECN VALENCIA,INST TECNOL QUIM,E-46071 VALENCIA,SPAIN

来源：

APPLIED CATALYSIS A-GENERAL | 1995年 / 128卷 / 01期

关键词：

TITANIUM BETA; EPOXIDATION; PHENYLETHYLENES; EPOXIDE OPENING; SOLVENT;

D O I：

10.1016/0926-860X(95)00094-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Phenylethylenes can be oxidized in methanol by hydrogen peroxide in the presence of zeolite beta containing titanium (TGP) to give predominantly glycol monomethyl ethers (arising from the acid-catalyzed opening up of the primary epoxide) accompanied by lower amounts of carbonyl compounds (derived from the oxidative C=C bond cleavage). These results contrast with those obtained using the same Ti-beta catalyst in acetonitrile or acetone as solvent or with those previously reported using titanium silicalite, where C=C bond rupture was the main process.

引用

页码：L7 / L11

页数：5

共 11 条

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