BLOCK POLYMERIZATIONS OF VINYL MONOMERS INITIATED BY TELECHELIC ISOPROPYL XANTHATE-TERMINATED POLYMERS AS MACROPHOTOINITIATOR - DESIGN OF BLOCK COPOLYMERS .2.

被引：41

作者：

NIWA, M

SAKO, Y

SHIMIZU, M

机构：

[1] Doshisha Univ, Kyoto, Jpn, Doshisha Univ, Kyoto, Jpn

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1987年 / A24卷 / 11期

关键词：

BLOCK COPOLYMERS - Molecular Weight - POLYMERS - Polymerization;

D O I：

10.1080/00222338708076948

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Both photopolymerization and thermal polymerization of a variety of vinyl monomers with bis(isopropylxanthogen) disulfide (BX) as initiator and as chain-transfer agent were carried out in benzene. Telechelic isopropyl xanthate-terminated polymers (TXP) having a different backbone have been used as macroinitiator for the polymerization of vinyl monomers. The rate of polymerization of the functional polymers was found to be markedly dependent on the monomer species: block polymerization of methyl acrylate or methyl methacrylate proceeded rapidly compared to the chain-extension polymerization of styrene.

引用

页码：1315 / 1332

页数：18

共 7 条

[1] NIWA M, 1986, J MACROMOL SCI CHEM, VA23, P433
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NIWA, M
MATSUMOTO, T
IZUMI, H
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1987, A24 (05): : 567 - 585
[3] NIWA M, 1970, SCI ENG REV DOSHISHA, V11, P105
[4] NIWA M, 1986, SCI ENG REV DOSHISHA, V26, P219
[5] RADICAL POLYMERIZATION OF STYRENE IN PRESENCE OF BIS(ISOPROPYL XANTHOGEN)
NOMA, K
NIWA, M
YOSHIDA, T
NESUMI, S
[J]. KOBUNSHI RONBUNSHU, 1977, 34 (02) : 97 - 102
[6] POLYMER DESIGN BY USING INIFERTERS .5. SYNTHESIS OF BLOCK CO-POLYMERS WITH ORGANIC SULFUR-COMPOUNDS AS INIFERTERS
OTSU, T
KURIYAMA, A
YOSHIDA, M
[J]. KOBUNSHI RONBUNSHU, 1983, 40 (10) : 583 - 588
[7] OTSU T, 1982, POLYM BULL, V7, P45

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