REDUCTION OF ALKENES AND AROMATIC NITRO-COMPOUNDS WITH BOROHYDRIDE EXCHANGE RESIN (BER) CATALYZED BY TRANSITION-METAL COMPOUNDS

被引：10

作者：

CHEN, JW

QIN, CQ

机构：

[1] Department of Chemistry, Hubei University, Wuhan

来源：

REACTIVE POLYMERS | 1992年 / 16卷 / 03期

关键词：

BOROHYDRIDE EXCHANGE RESIN (BER); POLYMERIC REDUCING AGENT; POLYMER-SUPPORTED REAGENT; TRANSITION METAL; METAL BORIDE;

D O I：

10.1016/0923-1137(92)90263-2

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Borohydride exchange resin (BER) with transition metal (Ni2+, Co2+, Cu2+, Cu+, Pd2+) catalysts reduced C = C double bond to single bonds, and aromatic nitro compounds to amines in ethanol solvent. A study of the effect of reaction conditions has been made, and the results discussed in terms of the mechanism of the reduction.

引用

页码：287 / 295

页数：9

共 15 条

[1]

CHEN JW, 1991, CHINESE CHEM LETT, V2, P127

[2]

CHEN JW, 1991, CHINESE CHEM LETT, V2, P125

[3]

COOK MM, 1978, POLYM PREPR AM CHEM, V19, P414

[4] SYNTHETICALLY USEFUL REACTIONS WITH METAL BORIDE AND ALUMINIDE CATALYSTS [J].