ENOL FORMATES - RUTHENIUM CATALYZED FORMATION AND FORMYLATING REAGENTS

被引:98
作者
NEVEUX, M [1 ]
BRUNEAU, C [1 ]
DIXNEUF, PH [1 ]
机构
[1] UNIV RENNES 1,CHIM COORDINAT ORGAN LAB,CNRS,URA D0415,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 05期
关键词
D O I
10.1039/p19910001197
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The one-step synthesis of the enol formates, isopropenyl,hex-1-en-2-yl, and alpha-methylenebenzyl formates, directly from terminal alkynes and formic acid with arene-ruthenium(II) catalysts is reported. They have been shown to be effective formylating reagents, under mild and neutral conditions, to produce formamides from primary and secondary amines, formylamino esters, and in the presence of a catalytic amount of imidazole, formates from alcohols or phenols.
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页码:1197 / 1199
页数:3
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