SYNTHESIS AND SOLUTION MULTINUCLEAR MAGNETIC-RESONANCE STUDIES OF HOMOLEPTIC COPPER(I) COMPLEXES OF SULFUR, SELENIUM AND TELLURIUM DONOR LIGANDS

被引：45

作者：

BLACK, JR ^{[1
]}

LEVASON, W ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 22期

关键词：

D O I：

10.1039/dt9940003225

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [CuL4][O3SCF3] (L = Me2S, Me2Se, Me2Te, Ph2S, Ph2Se or Ph2Te) and [Cu(L-L)2]PF6 [L-L = RE(CH2)2ER (E = S or Se, R = Me or Ph); RE(CH2)3ER (E = S, Se or Te; R = Me or Ph)] have been prepared and characterised by analysis, IR, and in particular multinuclear NMR spectroscopy (H-1, Se-77, Te-125 and Cu-63). Variable-temperature NMR studies have been used to probe various exchange processes occurring in solution. For a limited number of complexes Cu-63 NMR resonances have been observed, the first examples from Group 16 donor complexes.

引用

页码：3225 / 3230

页数：6

共 25 条

[1] SYNTHESES AND DYNAMIC NUCLEAR-MAGNETIC-RESONANCE STUDIES OF COMPLEXES OF TRIMETHYLPLATINUM(IV) IODIDE WITH DITELLUROETHER CHELATE LIGANDS [J].

ABEL, E ;

ORRELL, KG ;

SCANLAN, SP ;

STEPHENSON, D ;

KEMMITT, T ;

LEVASON, W .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, :591-595

[2] THE STEREODYNAMICS OF METAL-COMPLEXES OF SULFUR-CONTAINING, SELENIUM-CONTAINING, AND TELLURIUM-CONTAINING LIGANDS [J].

ABEL, EW ;

BHARGAVA, SK ;

ORRELL, KG .

PROGRESS IN INORGANIC CHEMISTRY, 1984, 32 :1-118

[3] MULTINUCLEAR NUCLEAR MAGNETIC-RESONANCE STUDIES OF TRIMETHYL-PLATINUM(IV) COMPLEXES WITH ORGANOCHALCOGEN LIGANDS [J].

ABEL, EW ;

ORRELL, KG ;

PLATT, AWG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (11) :2345-2351

[4] SULFUR-LIGAND-METAL COMPLEXES .4. COPPER-COMPLEXES WITH BIDENTATE TERTIARY-PHOSPHINE SULFIDE AND SELENIDE LIGANDS AND CRYSTAL-STRUCTURE OF A 3-CO-ORDINATE COPPER(1) COMPLEX [J].

AINSCOUGH, EW ;

BERGEN, HA ;

BRODIE, AM ;

BROWN, KA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (17) :1649-1656

[5] SULFUR-LIGAND-METAL COMPLEXES .8. "BIS(DIPHENYLPHOSPHINOTHIOYL)METHANE COMPLEXES OF COPPER [J].

AINSCOUGH, EW ;

BRODIE, AM ;

BROWN, KL .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (07) :1042-1047

[6] SULFUR LIGAND METAL-COMPLEXES .6. COPPER-COMPLEXES OF 2,5-DITHIAHEXANE AND 3,6-DITHIAOCTANE [J].

AINSCOUGH, EW ;

BRODIE, AM ;

PALMER, KC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (22) :2375-2381

[7] COPPER COORDINATION TO THIOETHER LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF BIS(2,5-DITHIAHEXANE)COPPER(II) BIS(TETRAFLUOROBORATE) AND BIS(3,6-DITHIAOCTANE)COPPER(I) TETRAFLUOROBORATES [J].

BAKER, EN ;

NORRIS, GE .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (09) :877-882

[8] TRIFLUOROMETHYL SULFATES OF TIN [J].

BATCHELOR, RJ ;

RUDDICK, JNR ;

SAMS, JR ;

AUBKE, F .

INORGANIC CHEMISTRY, 1977, 16 (06) :1414-1417

[9] SYNTHESIS AND SOLUTION MULTINUCLEAR NUCLEAR-MAGNETIC-RESONANCE STUDIES OF HOMOLEPTIC COPPER(I) COMPLEXES OF GROUP-15 DONOR LIGANDS [J].

BLACK, JR ;

LEVASON, W ;

SPICER, MD ;

WEBSTER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (20) :3129-3136

[10] COORDINATION CHEMISTRY OF HIGHER OXIDATION-STATES .35. SYNTHETIC, SPECTROSCOPIC, AND ELECTROCHEMICAL STUDIES OF SOME MER-[OSL3X3] [OSL3X3]+ AND FAC-[OSL3X3]/[OSL3X3]+ SYSTEMS (L = PR3, ASR3, SBR3, OR PYRIDINE-X = CL OR BR) - CRYSTAL-STRUCTURE OF FAC-[OS(PET2PH)3CL3].CH2CL2 [J].

CIPRIANO, RA ;

LEVASON, W ;

MOULD, RAS ;

PLETCHER, D ;

WEBSTER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (08) :2609-2616

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